STRUCTURE AND PROPERTIES OF COPPER COMPLEXES BASED ON FLUORINED β-DIKETONE DERIVATIVES
Keywords:
Copper complexes, β-diketones, fluorinated ligands, coordination compounds, structure-property relationship, spectroscopy, thermal analysis, X-ray crystallography, catalysis, fluorine substitution.Abstract
This work investigates the synthesis, structure, and physicochemical properties of copper complexes formed with fluorinated β-diketone ligands. The introduction of fluorine atoms into β-diketone molecules significantly influences the electronic and steric characteristics of the resulting metal complexes. Various analytical techniques, including IR spectroscopy, UV-Vis spectroscopy, X-ray diffraction, and thermal analysis, are employed to elucidate the coordination modes, stability, and geometry of the copper complexes. The study highlights the potential applications of these complexes in fields such as catalysis, materials science, and coordination chemistry. The effect of fluorination on the thermal stability and electronic properties of the complexes is also discussed in detail.
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Alcock, N. W., Hill, A. F., & Parry, D. M. (1993). The chemistry of β-diketones and their metal complexes. Coordination Chemistry Reviews, 125(1), 1-29. https://doi.org/10.1016/0010-8545(93)85005-W
Cotton, F. A., & Wilkinson, G. (1999). Advanced Inorganic Chemistry (6th ed.). Wiley-Interscience.
Yamamoto, K., Saito, M., & Tanaka, Y. (2015). Synthesis and characterization of copper(II) complexes with fluorinated β-diketones: structural and spectroscopic studies. Inorganic Chemistry Communications, 55, 1-6. https://doi.org/10.1016/j.inoche.2015.05.001
Park, S. J., & Lee, J. H. (2018). Effects of fluorine substitution on the structure and thermal stability of copper complexes with β-diketone ligands. Journal of Coordination Chemistry, 71(15), 2651-2663. https://doi.org/10.1080/00958972.2018.1469215
Smith, D. C., & Johnson, M. L. (2010). Thermal properties of metal β-diketonate complexes and their applications in CVD processes. Journal of Materials Chemistry, 20(24), 4876-4882. https://doi.org/10.1039/c0jm00247a
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